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A mode field adapter (MFA) fabricated by the thermal expanded core (TEC) technique is investigated. Firstly, the mode field characteristics of the TEC large mode area fiber (LMAF) are analyzed. Compared with the single-mode fiber (SMF), the mode field diameter of the LMAF enlarged slower than that of the SMF. Secondly, the mode field characteristics of the different fibers with TEC treatment are discussed. Thirdly, the transmission efficiency of the MFA fabricated by the SMF and LMAF is also investigated. Finally, we used the 6/125 μm SMF and 15/130 μm LMAF to fabricate an MFA with transmission efficiency of 92% and the handling power as high as 100 W.