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通过邻羧苯乙酸、1,10-邻菲啰啉及硝酸镉的溶剂热反应合成了2个配合物:[Cd(phen)(chdc)]n(1)和[Cd(phen)(chdc)(H2O)]n(2)。X-射线单晶衍射显示:1是梯状双链结构;2是单链结构,单链再通过氢键连接成双链。虽然1和2的组分相似,但它们在固态条件下的荧光发射却大不一样,可能在光化学方面有潜在的应用。
Two complexes of [Cd (phen) (chdc)] n (1) and [Cd (phen) (chdc)] were synthesized by the solvothermal reaction of ortho- carboxyphenylacetic acid, 1,10-phenanthroline and cadmium nitrate. (H2O)] n (2). X-ray single crystal diffraction shows that: 1 is a ladder-like double-stranded structure; 2 is a single-stranded structure, which is double-stranded by hydrogen bonding. Although components 1 and 2 are similar, their fluorescence emission under solid state conditions is quite different and may have potential applications in photochemistry.