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Zn3(PhCH=CHCOO)6(phen)2.H2O晶体具有与锰氧化物及锰氢氧化物类似的微结构,在生成环境与晶体化学微结构方面有明显的环境属性,是一种新生环境矿物.为研究其纳米晶结构、最佳纳米尺度和环境矿物属性,在溶液法合成该配合物晶体的基础上,采用纳米晶参数计算方法,对该配合物纳米级微粒的晶胞数、原子数、表面原子数和表面活性随微粒在纳米尺度范围内的变化进行了计算,对比锰氢氧化物结构,发现该配合物晶体活性、表面效应与颗粒尺度有密切关系,内部结构具有鲜明的环境属性.结合晶体颗粒的比表面积与总原子数相对颗粒尺度的变化关系,理论上确定了该颗粒最佳纳米化尺度为138nm,为此类物质纳米晶在环境方面的研究应用奠定了基础.
Zn3 (PhCH = CHCOO) 6 (phen) 2.H2O crystals have similar microstructure to manganese oxides and manganese hydroxides, and have obvious environmental properties in terms of formation environment and crystal chemical microstructure. In order to study its nanocrystalline structure, the best nanoscale and environmental mineral properties, based on the solution synthesis of the crystal of the complex, the nanocrystalline parameters were used to calculate the number of cells, the number of atoms , The number of surface atoms and the surface activity were calculated with the change of particle size in the nanoscale. Comparing the structure of manganese hydroxide, it was found that the crystal structure activity, surface effect and particle size of the complex are closely related to each other. The internal structure has distinct environmental attributes According to the relationship between the specific surface area of crystal particles and the total number of particles, the optimal nanocrystallization size of the particles is 138 nm, which lays the foundation for the application of these nanocrystals in the environment.