【摘 要】
：
The compound (SiCI3)2Fe(CO)4 was synthesized and structurally characterized by X-ray single-crystal diffraction. It crystallizes in monoclinic, space group P21/
【机 构】
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Applied Chemistry Department
【基金项目】
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国家高技术研究发展计划(863计划);江苏省自然科学基金;Foundation for Liu Da Ken Cai of Jiangsu Province;State Postdoctoral Foundation of China;the Postdoctoral Foundation of Jiangsu Province
论文部分内容阅读
The compound (SiCI3)2Fe(CO)4 was synthesized and structurally characterized by X-ray single-crystal diffraction. It crystallizes in monoclinic, space group P21/n with a = 8.287(2), b = 9.829(2), c = 9.042(2) A, β = 96.19(3)°, V = 732.2(3) A3, C4Cl16FeO4Si2, Mr = 436.77, Z = 2, Dc=1.981 g/cm3, F(000) = 424, μ(MoKa) = 2.282 mm-1, the final R = 0.048 and wR = 0.164 for 1109 observed reflections (I > 2σ(I)). The crystal structure of (SiCl3)2Fe(CO)4 reveals that the Si(1)-Fe-Si(1)a sequence is linear and perpendicular to the Fe(CO)4 cross-shaped plane.
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