甲烷干气重整反应中镍基催化剂上表面积碳研究

来源 :天然气化学 | 被引量 : 0次 | 上传用户：YNiit562552379

【摘要】

：

镍基催化剂上积碳是甲烷干气重整反应急需解决的反应等方法系统研究了镍基催化剂表面积碳的形态和特点.热力学研究表明,在573 K到1273 K的温度范围内,催化剂的表面积碳是不可

【作者】

：

丁荣刚阎子峰宋林花刘欣梅

【机构】

：

石油大学重质油加工国家重点实验室山东东营

【出处】

：

天然气化学

【发表日期】

：

2004年期

【关键词】

：

积碳镍基催化剂二氧化碳甲烷重整 carbon deposition nickel catalyst carbon dioxide methane ref

【基金项目】

：

CNPC Innovation Foundation of Young Scientists;

下载到本地 , 更方便阅读

下载此文赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

镍基催化剂上积碳是甲烷干气重整反应急需解决的反应等方法系统研究了镍基催化剂表面积碳的形态和特点.热力学研究表明,在573 K到1273 K的温度范围内,催化剂的表面积碳是不可避免的.TPSR、XPS和TPD研究表明,甲烷在催化剂表面裂解将形成至少三种碳物种:CaCβ和Cy.这三种碳物种具有不同的表面迁移能力、热稳定性和反应活性.其中,Cα物种在甲烷干气重整反应中是一种非常活泼和重要的中间体;cy物种则可能是表面积碳的前驱物;部分脱氢的Cβ物种能够与H2或CO2反应生成CH4或CO.

其他文献

A Study of the Electrochemistry of Two Biacridine Derivatives and Their Application

本文通过对荣华二采区10

期刊

Biacridine derivativesElectrochemistryTryptophanHistidine

The First Principle Calculation of Green-Kubo Formula with the Two-Time Ensemble Technique

为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7

期刊

two-time ensemble techniqueGreen-Kubo formula

Apoptosis inducing effects of arsenic trioxide on human bladder cancer cell line BIU-87

目的观察三氧化二砷(As2O3)对人膀胱癌细胞的诱导凋亡作用并探讨其机制。方法采用细胞计数和MTT法检测As2O3对人膀胱癌细胞株BIU-87的生长抑制作用；采用3H-TdR掺入法检测癌细

期刊

三氧化二砷膀胱癌BIU-87细胞凋亡arsenic trioxidebladder neoplasmsBIU-87 cellapoptosis三氧

The Normal- and Antinormal-Ordered Decomposition Formulas of Multimode Exponential Operators

We obtain the normally ordered form of the general multimode exponential operator by means of parameter differentiation method and its antinormally ordered form

期刊

multimode exponential operatorordered product of operators

TRANSIENT EFFECT OF A BOGER FLUID FLOWING AROUND A CONFINED CYLINDER

This paper is concerned with the numerical simulation of the transient effect of an inertialess Boger fiow past a confined circular cylinder and the comparison

期刊

Transient effectFlow around a cylinderLagrangian-Eulerian algorithmOldroyd-B

Tensor Polarization t20 of the Deuteron and the ρπrγ Process

Tensor polarization t20 of the deuteron is calculated on the basis of a hybrid quark-hadron model. A relativistic wavefunction of the deuteron is used to calcul

期刊

tensor polarization t20sign of ρπrγ coupling constant

FORMATION OF MESOPHASE MONO-DOMAINS AND MICRO-STRUCTURES IN THIN FILMS OF A SERIES OF COPOLYETHERS C

The structural and morphological evolution of mono-domains in thin films has been investigated for a series of liquid crystalline (LC) copolyethers. The copolye

期刊

Main-chain liquid crystalline polymerStructureMorphology

CS2 +( 2 Πg )的(1+1)光解离动力学研究

在气束条件下,利用483.2 nm的激光(3+1)共振增强多光子电离(REMPI)CS2分子以产生CS2+离子源,用另一束可调谐激光在424～482 nm内,通过对CS2+( 2 Πg)(1+1)双光子共振解离产生的

期刊

CS2+光解离光碎片激发

Effects of the Specific Area and the Thermal Stability of a Polymer on the Catalytic Activities of P

Co-Pd bimetallic catalysts immobilized with four kinds of resins with different specific areas were prepared by means of the solvated metal atom impregnation (S

期刊

Cobalt-palladium catalystDiacetone alcohol hydrogenationFuel cell electrode

Fission and Fusion of Solitons for the (1+1)-Dimensional Kupershmidt Equation

By means of the heat conduction equation and the standard truncated Painlevé expansion, the (1+1) dimensional Kupershmidt equation is solved. Some significant

期刊

truncated Painlevé expansion(1+1)-dimensional Kupershmidt equationresonant sol

甲烷干气重整反应中镍基催化剂上表面积碳研究

与本文相关的学术论文