[As3M(As3Pb3)]3-(M =Nb,Ta):Ternary Heterometallic Clusters with Early Transition Metal Atoms and Aro

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Main observation and conclusionrnTwo ternary clusters,[As3Nb(As3Pb3)]3-1 and [As3Ta(As3Pb3)]3-2,were directly extracted from “K8NbPbAs5” and “K8TaPbAs5” inter-metallic solid in the presence of ethylenediamine and 2.2.2-crypt,respectively.Both 1 and :2,comprising an electron-poor early tran-sition metahatom Nb or Ta coordinated to a As3 triangle and a bowl-like As3Pb3,were characterized by single crystal X-ray diffraction,energy dispersive X-ray (EDX) and electrospray ionization mass-spectrometry (ESI-MS).They also represent the first examples of the Pb-As hybrid in solution-based Zintl anion chemistry and DFT calculations revealed a σ-aromaticity of the [Pb3]2-unit.
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