Effect of rubrene:P3HT bilayer on photovoltaic performance of perovskite solar cells with electrodep

来源 :能源化学 | 被引量 : 0次 | 上传用户:lgfgdf
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Improved photovoltaic performance of perovskite solar cells is demonstrated through the synergistic effect of electrodeposited ZnO nanorods and rubrene:P3HT bilayer as electron and hole-transporting layers,respectively.Highly crystalline ZnO nanorods were obtained by electrochemical deposition in a chloride medium.Additionally,rubrene interlayer was able to passivate or cover the grain boundaries of perovskite film effectively that led to reduced leakage current.A perovskite solar cell optimized with ZnO nanorods and rubrene:P3HT bilayer achieved a maximum efficiency of 4.9% showing reduced hysteresis behavior compared with the device having P3HT as the only hole-transporting layer.The application of longer nanorods led to better perovskite infiltration and shorter charge carrier path length.These results high-light the potential of electrodeposited ZnO nanorods and rubrene:P3HT bilayer as charge selective layers for efficient perovskite solar cells.
其他文献
Pyrolyzed Fe-Nx/C materials derived from Fe-doped ZIF-8 are recently emerged as promising alternatives to noble metal platinum-based catalysts towards oxygen reduction reaction (ORR) and elucidating the dependacne of Fe source on the active site structure
Three new organic dyes based on triphenylamine with a structure of A-D-A-D-A (D1),A-D-A (D2) and D-A (D3) were designed,theoretically calculated and synthesized for dye-sensitized solar cells.Dye D1 exhibits a broader absorption than D2 and D3,due to the
Hybrid adsorbents for CO2 capture were prepared by coassembling laponite (LP) nanosheets and 1-nbutyl-3-methylimidazolium chloride (BMIMCl).The prepared BMIMCl/LP layered hybrids were systematically characterized.The interlayer distance of the BMIMCl/LP l
Controlling the concentration of defects in reduced graphene oxide (rGO) to tailor its electrical and physicochemical properties has remained a significant challenge.We report that extent of microwave (MW)-driven annealing of rGO is influenced significant
Energy storage is pivotal for the continuous utilization of solar energy suffering from the intermittency issue.Herein,we demonstrate a solar rechargeable flow cell (SRFC) based on photoelectrochemical regeneration of vanadium redox species for in-situ so
Electron transport layers (ETLs) in perovskite solar cells (PSCs) are a key factor to determine the photovoltaic performance.Herein,we demonstrate preparation of ZnO/ZnS core-shell composites through directly synthesizing ZnS on the ZnO nanoparticles in s
Mixed metal oxides in the nanoscale are of great interest for many aspects of energy related research topics as water splitting,fuel cells and battery technology.The development of scalable,cost-efficient and robust synthetic routes toward well-defined so
Lithium-sulfur (Li-S) batteries have attracted much attention due to their ultrahigh theoretical specific capacity.However,serious capacity attenuation caused by shuttle effect still inhibits the performance improvement.Herein,a modified separator consist
The goal of this study was to develop and design a composite proton exchange membrane (PEM) and membrane electrode assembly (MEA) that are suitable for the PEM based water electrolysis system.In particular,it focuses on the development of sulphonated poly
Metal sulphide electrocatalyst is considered as one of the most promising low-cost candidates for oxygen evolution reaction (OER).In this work,we report a novel free-standing Cu2S branch array via a facile TiO2-induced electrodeposition-sulfurization meth