【摘 要】
：
Reactions of 5-(p-aminophenyl)- 10,15,20-triphenyl porphyrin (1) with Ru 3(CO) 12 or M(OCOCH 3) 2 (M=Ni, Mn) afforded metalloporphyrins (4-6), respect
【出 处】
：
Chinese Journal of Chemistry
论文部分内容阅读
Reactions of 5-(p-aminophenyl)- 10,15,20-triphenyl porphyrin (1) with Ru 3(CO) 12 or M(OCOCH 3) 2 (M=Ni, Mn) afforded metalloporphyrins (4-6), respectively. 6-Deoxy-6-iodo-β-cyclodextrin (2) and mono(6-O-tri~fluoro~methane~sulfonyl) permethylated β-cyclodextrin (3) reacted with complexes 4-6 to give β-cyclodextrin bonded metal porphyrins (7-9) and permethylated β-cyclodextrin bonded me-tal porphyrins (10-12) respectively. These new complexes were identified by MS, IR, UV-visible and 1H NMR spectra, and elemental analysis.
Reactions of 5- (p-aminophenyl) -10,15,20-triphenyl porphyrin (1) with Ru 3 (CO) 12 or M (OCOCH 3) 2 (M = Ni, Mn) afforded metalloporphyrins 6-Deoxy-6-iodo-β-cyclodextrin (2) and mono (6-O-tri ~ fluoro ~ methane ~ sulfonyl) permethylated β-cyclodextrin These new complexes were identified by MS, IR, UV-visible and 1H NMR spectra, and elemental analysis.
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