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A new complex, [Ni(L)2]·2(H2O) I (HL = 2-iminomethyl-6-methoxyphenol), has been synthesized and structurally determined. The crystal belongs to the trigonal system, space group R 3 with a = 1.9341(3), b = 1.9341(3), c = 1.2048(2) nm, V = 3.9029(11) nm3, Mr = 395.05, Z = 9, Dc = 1.513 g·cm-3, F(000) = 1854, μ = 1.153 mm-1 and S = 1.014. Each NiII atom is four-coordinated by two N and two O atoms from two different L-anions to give a slightly distorted square-plane geometry. The complex forms a 3-D network structure through N-H···O and O-H···O hydrogen bonds containing an interesting six-membered water ring.
A new complex, [Ni (L) 2] · 2 (H2O) I (HL = 2-iminomethyl- 6-methoxyphenol), has been synthesized and structurally determined. The crystal belongs to the trigonal system, space group R 3 with a = 1.9341 (3), b = 1.9341 (3), c = 1.2048 (2) nm, V = 3.9029 (11) nm3, Mr = 395.05, Z = 9 and Dc = 1.513 g · cm- = 1854, μ = 1.153 mm-1 and S = 1.014. Each NiII atom is four-coordinated by two N and two O atoms from two different L-anions to give a slightly distorted square-plane geometry. The complex forms a 3- D network structure through NH ··· O and OH ··· O hydrogen bonds containing an interesting six-membered water ring.