Ti-Si-N films prepared by magnetron sputtering

来源 :Rare Metals | 被引量 : 0次 | 上传用户:ffgghhaz
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
A film growth mechanism, expressed in terms of depositing hard films onto the soft substrate, was proposed. Multicomponent thin films of Ti-Si-N were deposited onto Al substrate with a double-target magnetron sputtering system in an Ar-N 2 gas mixture. The Ti-Si-N films were investigated by characterization techniques such as X-ray diffraction (XRD), atomic force microscope (AFM), electron probe microanalyzer (EPMA), scratch test and nanoindentation. The as-deposited films have a good adhesion to Al substrate and appear with smooth and lustrous surface. The films show nanocomposite structure with nano TiN grains embedded in an amorphous SiN x matrix. The maximum hardness of the films was achieved as high as 27 GPa. The influences of the N 2 flow rate and substrate temperature on the growth rate and quality of the films were also discussed. For all samples, the Ar flow rate was maintained constant at 10 ml min 1 , while the flow rate of N 2 was varied to analyze the structural changes related to chemical composition and friction coefficient. The low temperature in the deposited Ti-Si-N films favors the formation of crystalline TiN, and it leads to a lower hardness at low N 2 flow rate. At the same time, the thin films deposited are all crystallized well and bonded firmly to Al substrate, with smooth and lustrous appearance and high hardness provided. The results indicate that magnetron sputtering is a promising method to deposit hard films onto soft substrate. Multicomponent thin films of Ti-Si-N were deposited onto Al substrate with a double-target magnetron sputtering system in an Ar-N2 gas mixture The Ti-Si-N films were investigated by characterization techniques such as X-ray diffraction (XRD), atomic force microscope (AFM), electron probe microanalyzer (EPMA), scratch test and nanoindentation. adhesion to Al substrate and appear with smooth and lustrous surface. The films show nanocomposite structure with nano TiN grains embedded in an amorphous SiN x matrix. The maximum hardness of the films was achieved as high as 27 GPa. The influences of the N 2 flow rate and substrate temperature on the growth rate and quality of the films were also discussed. For all samples, the Ar flow rate was maintained at at least 10 ml min 1, while the flow rate of N 2 was varied to analyze the structural changes r elated to chemical composition and friction coefficient. The low temperature in the deposited Ti-Si-N films favors the formation of crystalline TiN, and it leads to a lower hardness at low N 2 flow rate. At the same time, the thin films deposited are all crystallized well and bonded firmly to Al substrate, with smooth and lustrous appearance and high hardness provided.
其他文献
本文阐述了低压蒸汽雾化 Y 型燃烧器的结构和特点,并介绍了这种燃烧器在东方红炼油厂大型加热炉上应用的情况,以及运行中遇到的问题和解决、调试方法。 This paper describe
目的研究分析本院洁净手术室(以下简称手术室)空气质量检测情况。方法选用10个手术室做空气对比,选择自然沉降法,于各时间段检测室内空气质量差异。结果术中细菌数含量显著增
摘要:高中体育教学需要师生间互动来加强教学效果。互动能够增加教学的趣味性,吸引学生注意力。教师在教学时,要学会应用多种互动方式进行课堂教学。此外教师还要注意在教学过程对学生进行反馈和评价。本文主要分析了关于课堂互动的三种方法,以此来帮助学生和教师在实际教学过程中更好的互动和学习。  关键词:师生互动;评价方式;情境教学  中图分类号:G633.96文献标识码:A 文章编号:1992-7711(20
第一台国产石蜡连续成型机于1970年投产后,改变了以往间歇式水冷板框石蜡成型机劳动强度大、技术落后的状况,相继在几个炼油厂采用。北京石油设计院除对冷却室的冷却系统作
在各项政策的引导之下,新课改在稳步推进之中,与之相对应的语文教学方法也应该与时俱进,通过教学方法的革新来提高教学效率,提高学生的综合语文素质。基于以上现状,情境教学
对纤维状催化剂ACF吸附SO2动力学进行了探讨,结果表明:ACF吸附速度快、吸附平衡时间短、平衡吸附量大;其结构变化对吸附动力学有影响;Bangham和Langmuir吸附速度方程在ACF对SO2吸附体系有一定的适用性. The kine
根据外贸部等部门“关于‘十五’期间进一步促进机电产品出口意见”的精神,以加入世贸组织为契机,协助企业开拓国际市场,帮助企业提高产品质量、出口效益和国际竞争力,切实
仿佛就在一夜之间,亚细亚大陆所有足球的迷惑都豁然开朗,欧洲足球已不再神秘。意大利足球至尊的光环下是来自东亚的神奇小子中田英寿的屡屡上佳表演,德国人足球强国的威严中
在稠油开发和油田管理中,为了保持地层的高渗透率,必须对完井液、洗井液和修井液进行细级过滤。本文作者针对所在单位研制的那套过滤精度达2μ的细过滤器的结构、原理以及确
当国奥队结束了登喜路杯的比赛3月1日又开始了新一轮集训的时候,所有的人目光都集中在了新国奥的这些小将们身上。这些在首次大考中有得有失,既有闪光亮点又有两负韩国遗撼