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测定锡酸钠中可溶锡时,为将四价锡还原成二价锡然后以标准碘酸钾-碘化钾溶液滴定总锡量。二价锡易被空气中的氧所氧化,所以滴定在二氧化碳气氛中进行,二氧化碳由改进后特制的锡还原装置发生。实验部分1 试剂: 所用试剂分析纯试剂,所用水均为蒸馏水。盐酸比重1.19 氢氧化钠溶液1%饱和碳酸氢钠溶液
Determination of tin in soluble tin, the tin is reduced to divalent tin and then standard potassium iodate - potassium iodide solution titration total tin. Bivalent tin is easily oxidized by the oxygen in the air, so the titration takes place in a carbon dioxide atmosphere, which takes place by a tailor-made tin reduction unit. Experimental part 1 Reagents: reagents used analytical reagent, the water used are distilled water. Hydrochloric acid Proportion 1.19 Sodium hydroxide solution 1% Saturated sodium bicarbonate solution