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The crystal of the title compound with formula C36H44Cl2F3Mo2NO8S2 (Mr = 10002.62) crystallized in monoclinic, space group P21/n, with a = 9.6184(1), b = 22.3476(2), c = 20.7758(2) ?, ( = 90.172(1)(, V = 4465.70(7) ?3, Z = 4, Dc = 1.491 g/cm3, F(000) = 2032, ( = 0.833 mm－1, Final R = 0.0665 and wR = 0.1650 for 5044 reflections with I >2.0( (I). The crystal structure revealed that the Mo2S2 core is planar, and the trifluoroacetic group acts as a bidentate bridging ligand and coordinates to two Mo atoms forming a five-membered ring plane, in which the Mo-Mo bond distance is 2.9222(9) ? and the O-C-O angle is 131.8(7)
The crystal of the title compound with formula C36H44Cl2F3Mo2NO8S2 (Mr = 10002.62) crystallized in monoclinic space group P21 / n with a = 9.6184 (1) b = 22.3476 (2) c = 20.7758 D = 1.491 g / cm3, F (000) = 2032, (= 0.833 mm-1, Final R = 0.0665 and wR = 0.1650 for 5044 reflections), V = 4465.70 (7)? 3, Z = with I> 2.0 ((I). The crystal structure revealed that the Mo2S2 core is planar, and the trifluoroacetic group acts as a bidentate bridging ligand and coordinates to two Mo atoms forming a five- membered ring plane, in which the Mo-Mo Bond distance is 2.9222 (9)? and the OCO angle is 131.8 (7)