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用 Bjerrnm-calvin pH 滴定技术,在35℃、用3∶1二氧六环:水溶液及离子强度恒定(0. 1MKNO_3) 的条件下测定了反式5-异戊基2-羟基二苯甲酮肟萃取剂与质子、铜(Ⅱ)、铁(Ⅲ)、钴(Ⅱ)、镍(Ⅱ)、锌(Ⅱ)的络合稳定常数.并测得反式3-仲丁基2-羟基二苯甲酮肟和反式5-仲丁基2-羟基二苯甲酮肟萃取剂与质子、铜(Ⅱ)的络合稳定常数.
The trans-5-isopentyl 2-hydroxybenzophenone was determined using Bjerrnm-calvin pH titration at 35 ° C with a 3: 1 dioxane: aqueous solution and a constant ionic strength (0.1 M KNO 3) (Ⅱ), iron (Ⅲ), cobalt (Ⅱ), nickel (Ⅱ) and zinc (Ⅱ) Benzophenone oxime and trans-5-sec-butyl 2-hydroxybenzophenone oxime extractants with proton and copper (Ⅱ) complex stability constants.