Correlation Analysis of the Fluorescence Data of Some Benzaldehyde Derivatives by the Dual-Parameter

来源 :Chinese Chemical Letters | 被引量 : 0次 | 上传用户:xxcdejingcai
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The fluorescence emission wavelength [λmax(em)] values of three types of benzaldehyde derivatives, namely, ethylene acetals (1-Ys), 4-nitrophenylhydrazones (2-Ys) and phenylhydrazones (3-Ys), have been measured. Correlation analyses by the dual-parameter equation show that the λmax(em) values of 1-Ys are mainly affected by the spin-delocalization effects of the substituents, while those of 2-Ys are mainly affected by the polar effects. However,those of 3-Ys are independent of the substituents. The fluorescence emission wavelength [λmax (em)] values ​​of three types of benzaldehyde derivatives, namely, ethylene acetals (1-Ys), 4-nitrophenylhydrazones (2-Ys) and phenylhydrazones (3-Ys), have been measured. Correlation analyzes by the dual-parameter equation show that the λmax (em) values ​​of 1-Ys are mainly affected by the spin-delocalization effects of the substituents, while those of 2-Ys are mainly affected by the polar effects. However, those of 3 -Ys are independent of the substituents.
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