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In this paper, the frequency-locking and threshold current-lowering effects of quantum cascade laser are studied and achieved. Combined with cavity-enhanced absorption spectroscopy, the noninvasive detection of H2 with a pre-pared concentration of 500 ppm in multiple dissolved gases is performed and evaluated. The high frequency selectivity of 0.0051 cm?1 at an acquisition time of 1 s allows the sensitive detection of the (1-0) S(1) band of H2 with a high ac-curacy of (96.53±0.29)%and shows that the detection limit to an absorption line of 4712.9046 cm?1 is approximately (17.26±0.63) ppm at an atmospheric pressure and a temperature of 20?C.