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A complex [Cu2Br2(L)2]n(1)(L=bis(2-pyrimidinylthio)methane)has been synthesized and structurally characterized.Complex 1 contains dinuclear Cu2Br2 units,which are linked by ditopic L to form a 2D layer structure with a 36-membered macrometallocycle.The adjacent layers are further connected through interpyrimidyl rings C-H … N and π-π interactions to give rise to a three-dimensional supramolecular structure.Complex 1 also displays strong green solid-state photoluminescence,due to metal-to-ligand charge-transfer(MLCT)at room temperature.CCDC:711434.
A complex [Cu2Br2 (L) 2] n (1) (L = bis (2- pyrimidinylthio) methane) has been synthesized and structurally characterized. Complex 1 contains dinuclear Cu2Br2 units, which are linked by ditopic L to form a 2D layer structure with a 36-membered macrometallocycle. The adjacent layers are further connected through interpyrimidyl rings CH ... N and π-π interactions to give rise to a three-dimensional supramolecular structure. Complex 1 also displays strong green solid-state photoluminescence, due to metal- to-ligand charge-transfer (MLCT) at room temperature. CCDC: 711434.