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Gibbs-Duhem方程式在溶液热力学中具有广泛的用途,对溶液中任一衡分子热力学性质M,它的普遍形式是: ((?)M/(?)T)_(P、X)dT+((?)M/(?)p)_(T、X)dp-∑(M_jd(?)_i)=0(1)
The Gibbs-Duhem equation has a wide range of uses in solution thermodynamics. The general form of the Gibbs-Duhem equation for the thermodynamic properties of any molecule in solution is: ((?) M / (?) T) M /? P) _ (T, X) dp-Σ (M_jd (?) _i) = 0