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用玻璃流动循环反应器研究了Fe_(4·9)Zn_(0·9)Mg_(0·1)(原子比)催化剂上丁烯-2氧化脱氧动力学。丁烯-2氧化脱氢制丁二烯,丁烯-2及丁二烯深度氧化生成CO_2的动力学用双分子反应强吸附的L-H机理方程描述。速度方程的参数用非线性最小二乘法估计。
The kinetics of oxidative deoxygenation of butene-2 on Fe_ (4. 9) Zn_ (0.9) Mg_ (0.1) (atomic ratio) catalyst was investigated using a glass flow reactor. Oxidative dehydrogenation of butene-2 to butadiene, butane-2 and butadiene The kinetics of deep oxidation to CO 2 is described by the L-H mechanism equation of strong adsorption by bimolecular reaction. The parameters of velocity equation are estimated by nonlinear least square method.