改性塿土对土壤有机污染物苯酚运移的阻滞模拟

来源 :农业工程学报 | 被引量 : 0次 | 上传用户:gqkhao
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为了防止和控制污染物在土壤中纵向迁移,保护地下水免受污染。该研究通过饱水土柱运移试验,用非反应性离子Cl-探求土柱参数弥散系数,并运用平均孔隙水流速和弥散系数求算反应性溶质苯酚的运移参数阻滞系数,探究十六烷基三甲基溴化铵(cetyltrimethylammonium bromide,CTMAB)改性土和原土对苯酚运移的阻滞效应,以及改性比例、pH值、离子强度等因素对苯酚在土柱中运移的影响。结果表明:以 CTMAB 改性黏化层塿土,显著增强了土壤对苯酚运移的阻滞能力。改性土对苯酚运移的阻滞能力随着改性比例的增加而增强,苯酚在100%改性土中运移的阻滞系数值是在原土中的26.06倍;pH值在6.0~8.0变化时,对苯酚在改性土中运移的阻滞作用影响不大;当离子强度在0.001~0.1 mol/L范围内,随着离子强度的增加,原土和改性土对苯酚运移的阻滞能力均减弱,原土对苯酚的阻滞系数由0.56降至0.37,100%改性土由17.57降至8.71。以100%改性比例制备的改性土在中性环境,离子强度为0.001 mol/L环境中对苯酚的阻滞效果最好。
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