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用蒸发溶液法从磷酸溶液中生长出不同掺锰量的五磷酸铈晶体。在合适的生长条件下可获得优质的光学晶体。用电子顺磁共振确定晶体中锰离子为二价。CeP_5O_(14)-Mn(II)的激发光谱和发射光谱表明,Ce~(3+)-Mn~(2+)间存在着能量转移。
With the evaporation of the solution method from the phosphoric acid solution was grown in varying amounts of doped manganese pentasodium crystal. High quality optical crystals are obtained under suitable growth conditions. Determination of manganese ion in crystals by electronic paramagnetic resonance is bivalent. The excitation and emission spectra of CeP_5O_ (14) -Mn (II) show that there is energy transfer between Ce ~ (3 +) - Mn ~ (2+).