Synthesis, Crystal Structure and Catalytic Activity of a Pd-PEPPSI Complex Bearing Bromine Group

来源 :结构化学 | 被引量 : 0次 | 上传用户：peilimin1989

【摘要】

：

A new Pd-PEPPSI complex(2) with the bromo groups on the para-positions of N-aryl moieties of NHC has been synthesized and characterized by NMR and X-ray single-

【作者】

：

李莹韩方外徐子扬王茹严晨昕欧尤静卢倩刘桂艳曾

【机构】

：

TianjinKeyLaboratoryofStructureandPerformanceforFunctionalMolecules

【出处】

：

结构化学

【发表日期】

：

2019年3期

【关键词】

：

Pd-PEPPSI COMPLEX crystal structure catalytic activity SUZUKI-MIYAURA CROSS-COUP

【基金项目】

：

the Natural Science Foundation of Tianjin (No 16JCYBJC19700),the National Natural Science Foundation of China (No. 21771138),the Foundation of Development Program of Future Expert in Tianjin Normal Un

下载到本地 , 更方便阅读

下载此文赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

A new Pd-PEPPSI complex(2) with the bromo groups on the para-positions of N-aryl moieties of NHC has been synthesized and characterized by NMR and X-ray single-crystal diffraction. Complex 2 crystallizes in monoclinic, space group P21/c with a = 11.8790(8

其他文献

Epicardial 冠的动脉在一个可卡因用户的内层的光滑的肌肉增生

Accelerated epicardial coronary artery atherosclerosis has been well-documented in cocaine users.There are only two reported cases of cocaine-associated diffuse

期刊

COCAINECoronaryarteryHYPERPLASIASMOOTHMUSCLECocaine Coronary artery Hy

Effect of Alkali Metal Ions（Li＋, Na＋ and K＋） on the Luminescent Properties of ZnTiO3：Eu3＋ Phosphors

A series of red emitting ZnTiO_3 phosphors co-doped with Eu~(3+) and alkali metal ions(Li~+, Na~+ and K~+) was prepared by sol-gel method. The crystal structure

期刊

碱金属离子红色荧光粉发光特性钛酸锌ZnTiO3透射电子显微镜溶胶-凝胶法晶体结构alkali metal ions phosphors Zn

思科“女首相”

那还是80年代初,27岁的Judy Estrin刚刚创立了自己的公司,一天接到地区法院的通知,要出庭担任一场诉讼的陪审员。再有两个星期,她的网络公司Bridge Communications就要展示第

期刊

副总裁网络业思科高科技公司地区法院陪审员网络公司应用技术法官合伙人

Brugada electrocardiographic 模式由发烧导致了

Brugada syndrome is a major cause of sudden death in young adults.Fever has been described to induce a Brugada-type electrocardiogram in asymptomatic patients w

期刊

BRUGADASYNDROMEPHENOTYPEFEVERELECTROCARDIOGRAMBrugada syndrome Phenotype

我的小时候(上集)

我就出生在北京,1972年的12月11号,在南城的回民医院。上学的时候好一阵子喜欢看《史记》,那帝王出生的时候总会有很多极邪乎的征兆:满室异香呀,飞龙在天呀。我曾很天真地问

期刊

数字图书馆穿越时空隧道

随着信息与网络通讯技术的飞速发展,文字、影像、音乐、视讯等各种文件资料大量产生,并开始通过互联网进行广泛地传播,在此情况下数字图书馆(DigitalLibrary)也应运而生。数

期刊

网络淘金热中的“送水人”——3721经营思路之管窥

前几天听到业内一位记者朋友评论,说目前很多网站都是用钱搅出的五彩泡沫,虚华但没有什么“干货”,后来谈到3721(www.3721.net),他却颇为赞赏,认为“确实还有点东西”。在人

期刊

Salmonella Berta myocarditis:Case report and systematic review of non-typhoid Salmonella myocarditis

AIM: To study trends in the epidemiology,clinical presentation,microbiology and prognosis of nontyphoid Salmonella(NTS) myocarditis.METHODS: We performed a syst

期刊

DIARRHEAMYOCARDITISSALMONELLANontyphoidDiarrhea Myocarditis Salmonella No

A Unique Heteronuclear Metal Organic Framework Based on Amino-acid and N-donor Ancillary Ligand: Syn

A novel heteronuclear metal organic framework(MOF) incorporating both transition and alkali metal ions, namely, {(Ni2K2L2·bipy]×6 H2O]×2 H2O}n(1,

期刊

hetero-nuclearcomplexN-phosphono-methylAMINOdiaceticacidelectricalconduct

pH Dependent Supramolecules Based on Co-crystallization of Pyrazine-2,3,5,6-tetracarboxylic Acid wit

Co-crystallization of pztcH_4 with 4,4?-bipyridine(4,4?-bipy) in pH = 3~4 and 1~2 gave two new binary molecular adducts: [(4,4?-bipy H2)(pztc H_2)](1) and [(4,4

期刊

分子间氢键共结晶PH依赖型X-射线单晶衍射吡嗪子基甲酸pyrazine-2356-tetracarboxylic acid 44＇-bi

Synthesis, Crystal Structure and Catalytic Activity of a Pd-PEPPSI Complex Bearing Bromine Group

与本文相关的学术论文