This paper presents the results of an application of a first-order conditional moment closure (CMC) approach coupled with a semi-empirical soot model to investigate the effect of various detailed combustion chemistry schemes on soot formation and destruction in turbulent non-premixed flames.A two-equation soot model representing soot particle nucleation,growth,coagulation and oxidation,was incorporated into the CMC model.The turbulent flow-field of both flames is described using the Favre-averaged fluid-flow equations,applying a standard k-ε turbulence model.A number of five reaction kinetic mechanisms having 50-100 species and 200-1000 elementary reactions called ABF,Miller-Bowman,GRI-Mech3.0,Warnatz,and Qin were employed to study the effect of combustion chemistry schemes on soot predictions.The results showed that of various kinetic schemes being studied,each yields similar accuracy in temperature prediction when compared with experimental data.With respect to soot prediction,the kinetic scheme containing benzene elementary reactions tends to result in a better prediction on soot concentrations in comparison to those contain no benzene elementary reactions.Among five kinetic mechanisms being studied,the Qin combustion scheme mechanism turned to yield the best prediction on both flame temperature and soot levels. This paper presents the results of an application of a first-order conditional moment closure (CMC) approach coupled with a semi-empirical soot model to investigate the effect of various detailed combustion chemistry schemes on soot formation and destruction in turbulent non-premixed flames. A two-equation soot model representing soot particle nucleation, growth, coagulation and oxidation, was incorporated into the CMC model. Turbulent flow-field of both flames is described using the Favre-averaged fluid-flow equations, applying a standard k-ε turbulence model. A number of five reaction kinetic mechanisms having 50-100 species and 200-1000 elementary reactions called ABF, Miller-Bowman, GRI-Mech 3.0, Warnatz, and Qin were employed to study the effect of combustion chemistry schemes on soot predictions.The results showed that of various kinetic schemes are studied, each exactly similar accuracy in temperature prediction when compared with experimental data .With respect to soot prediction, the k inetic scheme containing benzene elementary reactions to result in a better prediction on soot concentrations in comparison to those containing no benzene elementary reactions. Among five kinetic mechanisms being studied, the Qin combustion scheme mechanism turned to yield the best prediction on both flame temperature and soot levels.