论文部分内容阅读
One novel organic-inorganic hybrid materials with 4,4’-bipy ligands and copper chlorine coordination polymers as linkers,with new topology,{[Cu~I(4,4’-bipy)]_(10)Cl_2(SiW_(12)O_(40))_2}·6H_2O(1)(4,4’-bipy = 4,4’-bipyridine),has been hydrothermally synthesized. The single crystal X-ray structural analysis reveals that the structure of 1 is constructed from classical Keggin anions and[Cu~I(4,4’- bipy)]cations into a novel,three-dimensional(3D) polyoxometalates(POMs)based network.From the topological view,compound 1 is a novel(3.4~4.5~2.6~3)(3~2.4~4.5~6.6~9) topology.The electrochemical and photocatalysis properties of 1 have been investigated in details.
One novel organic-inorganic hybrid materials with 4,4’-bipy ligands and copper chlorine coordination polymers as linkers, with new topology, {[Cu ~ I (4,4’-bipy)] ) O_ (40)) _2} · 6H_2O (1) (4,4’-bipy = 4,4’-bipyridine), has been hydrothermally synthesized. The single crystal X-ray structural analysis reveals that the structure of 1 is constructed from classical Keggin anions and [Cu~I (4,4’-bipy)] cations into a novel, three-dimensional (3D) polyoxometalates (POMs) based network. ~ 2.6 ~ 3) (3 ~ 2.4~4.5 ~ 6.6 ~ 9) topology.The electrochemical and photocatalysis properties of 1 have been investigated in details.