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The reduction of diacyl diselenides by samarium diiodide led to the production ofsamarium acylselenolates, which reacted with a,β-unsaturated esters or nitriles to give β-selenoesters or selenonitriles under mild and neutral conditions.
The reduction of diacyl diselenides by samarium diiodide led to the production ofsamarium acylselenolates, which reacted with a, β-unsaturated esters or nitriles to give β-selenoesters or selenonitriles under mild and neutral conditions.