The two-dimensional material graphene shows its extraordinary potential in many application fields.As the most effective method to synthesize large-area monolayer graphene, chemical vapor deposition has been well developed; however, it still faces the challenge of a high occurrence of multilayer graphene, which causes the small effective area of monolayer graphene. This phenomenon limits its applications in which only a big size of monolayer graphene is needed. In this paper, by introducing a redistribution stage after the decomposition of carbon source gas to redistribute the carbon atoms dissolved in Pt foils, the number of multilayer flakes on the monolayer graphene decreases. The mean area of monolayer graphene can be extended to about 16 000 m2, which is eight times larger than that of the graphene grown without the redistribution stage. A Raman spectrograph is used to demonstrate the high quality of the monolayer graphene grown by the improved process. The two-dimensional material graphene shows its extraordinary potential in many application fields. As the most effective method to synthesize large-area monolayer graphene, chemical vapor deposition has been well developed; however, it still faces the challenge of a high occurrence of multilayer graphene , this causes the small effective area of ​​monolayer graphene. This phenomenon limits its applications in which only only a big size of monolayer graphene is needed. In this paper, by introducing a redistribution stage after the decomposition of carbon source gas to redistribute the carbon- in Pt foils, the number of multilayer flakes on the monolayer graphene decreases. The mean area of ​​monolayer graphene can be extended to about 16 000 m2, which is eight times larger than that of the graphene grown without the redistribution stage. A Raman spectrograph is used to demonstrate the high quality of the monolayer graphene grown by the improved process.