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在无探针条件下,用电化学方法测定了SDS/BA/H2O三组分体系的扩散系数和扩散活化能.结果表明,L1区域由O/W结构做乳液与油、水观连续结构徽乳液(BI)两个小区域组成,并不是单一的O/W区域.在O/W区域内,微乳液以液滴状态存在,具有较好的扩散性能和较小的扩散活化能;在BI区域,水与BA同作为连续相与被增溶相存在,统合体系呈网络结构,扩散性能较低,扩散活化能较大.
In the absence of probe, the diffusion coefficient and diffusion activation energy of SDS / BA / H2O three-component system were determined by electrochemical method. The results showed that the L1 region was composed of two small regions of O / W structure emulsion and oil and water continuous structure Emulsion (BI), not a single O / W region.In the O / W region, In the BI region, water and BA are the same as continuous phase and solubilized phase, and the integrated system has a network structure with low diffusion ability and diffusive activation energy Larger.