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A new metal-organic framework,{Zn[Zn3(BTA)3(μ3-OH)(H2O)3]2}n 1,has been synthesized under hydrothermal reaction of ZnCl2 and bis(5-tetrazolyl)amine(H2BTA),and characterized by elemental analysis,FT-IR,Raman spectrum,X-ray single-crystal diffraction,TGA an