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By means of a highly sensitive electrolytic cell installed in the ESR cavity, the authors investi-gated in situ the kinetic behavior of the primary electroreduction product (a radical anion) in a sol-vent mixture of water and ethanol over a wide range of pH. For the first time they observed somefurther complex kinetic behaviors of the electroreduction process of nitrobenzene. Through a study ofthe behavior of the radical anion (φ-NO_2~-.) with variations of pH, concentration of nitrobenzene(φ-NO_2) and electroreduction potential, they advanced a reaction scheme of the electroreduction ofnitrobenzene and simulated the experimental curves in order to evaluate the kinetic parameters of thereaction steps concerned.
The means of a highly sensitive electrolytic cell installed in the ESR cavity, the authors investi-gated in situ the kinetic behavior of the primary electroreduction product (a radical anion) in a sol-vent mixture of water and ethanol over a wide range of pH . For the first time they observed somefurther complex kinetic behaviors of the electroreduction process of nitrobenzene. Through a study of the behavior of the radical anion (φ-NO_2 ~ -.) With variations of pH, concentration of nitrobenzene (φ-NO_2) and electroreduction potential, they advanced a reaction scheme of the electroreduction of nitrobenzene and simulated the experimental curves in order to evaluate the kinetic parameters of thereaction steps concerned.