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2-羟基萘甲醛苯甲酰腙(H2L)由2-羟基萘甲醛和苯甲酰肼在乙醇溶液中制得。利用H2L分别合成了钼和钒的配合物,[MoO2(EtOH)L](1)和[VO(OMe)L(MeOH)](2),并测定了它们的晶体结构。配合物1和2是类似的结构单元,钼和钒都采取扭曲的八面体配位构型。
2-Hydroxynaphthaldehyde Benzoylhydrazone (H2L) is prepared from 2-hydroxynaphthaldehyde and benzoylhydrazide in ethanol. The complexes of molybdenum and vanadium [MoO2 (EtOH) L] (1) and [VO (OMe) L (MeOH)] were synthesized by H2L and their crystal structures were determined. Complex 1 and 2 are similar structural units, and both molybdenum and vanadium adopt a twisted octahedral coordination structure.