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Two molybdophosphate compounds,[Ni(bim)3]2[H2P2Mo5O23]·2H2O 1 and [Zn(bpy)2]2[Zn(bpy)(H2O)]2Zn[Mo6O12(OH)3(HPO4)4]2·9H2O 2 (bim = 2,2’-biimidazole,bpy = 2,2’-dipyridyl),have been synthesized under hydrothermal conditions and structurally characterized by elemental analysis,TG,and IR. The single-crystal X-ray analysis exhibits that 1 consists of one [H2P2Mo5O23]4-,two [Ni(bim)3]2+ cations and two lattice water molecules,while 2 is constructed from one sandwich-type [ZnP4Mo6] anion modified by four Zn-bpy complexes and nine lattice water molecules. The electrochemical behaviors of compounds 1 and 2 have been studied in detail based on solid bulk modified carbon paste electrodes of compound (CPEs).
Two molybdophosphate compounds [Ni (bim) 3] 2 [H2P2Mo5O23] · 2H2O 1 and [Zn (bpy) 2] 2 [Zn (bpy) (H2O)] 2Zn [Mo6O12 (OH) 3 9H2O 2 (bim = 2,2’-biimidazole, bpy = 2,2’-dipyridyl), have been synthesized under hydrothermal conditions and structurally characterized by elemental analysis, TG, and IR. The single-crystal X-ray analysis exhibits that 1 consists of one [H2P2Mo5O23] 4-, two [Ni (bim) 3] 2+ cations and two lattice water molecules, while 2 is constructed from one sandwich-type [ZnP4Mo6] anion modified by four Zn-bpy complexes and nine lattices water molecules. The electrochemical behaviors of compounds 1 and 2 have been studied in detail based on solid bulk modified carbon paste electrodes of compound (CPEs).