论文部分内容阅读
作者等在前报(本志,1960,80,(12)1686)中以6,8-二卤代辛酸酯类与种种巯基化剂合成α—硫辛酸的反应中,几乎皆有低沸点物生成,此物为bp_(0.1)120-135°淡黄色的油状液,推断此物为巯基化不完全的付产物。为了証实此物是否为杂硫环丁基(Thiacyclobutyl)化合物并加以利用而进行了有关的研究。作者等首先按一般方法合成了据推断与反应付产物相同的杂硫环丁基化合物经过元素分
The reaction of the 6,8-dihalooctanoic acid ester with various thiolation reagents in the former report (Hyogo, 1960, 80, (12) 1686) synthesized almost all the low-boiling substances Generated, this is bp_ (0.1) 120-135 ° light yellow oily liquid, this is concluded that the thiolation incomplete by-products. In order to confirm whether this compound is Thiacyclobutyl compound and make use of it, the related research was done. The authors first synthesized by the general method has been inferred that the same reaction with the product of miscellaneous sulfur sulfur butyl compounds through the elemental