An artificial tribological layer was formed on the worn surface during sliding,through supplying MoS_2,Fe_2O_3 or their equiponderant mixtures onto the sliding interface of H13/GCr15 steels.The effect of this tribological layer on the wear behavior of H13 steel was studied.The worn surfaces and subsurfaces of H13 steel were thoroughly characterized by using X-ray diffraction(XRD),scanning electron microscopy(SEM)and energy dispersive spectrometry(EDS);the wear mechanisms were explored.The research results demonstrated that tribological layer did not exist during sliding of H13 steel with no additive,but it formed with the addition of MoS_2,Fe_2O_3 or their equiponderant mixtures.When there was no tribological layer,the wear rate rapidly increased with an increase of the load.In this case,adhesive and abrasive wear prevailed.As the additives were supplied,the artificial tribological layer was observed to be immediately formed and stably existed on worn surfaces.This tribological layer presented an obvious protective function from wear and friction.Hence,the wear rate and friction coefficient were significantly decreased.MoS_2 as tribological layer seemed to present more obvious protective function than Fe_2O_3.By supplying their mixture,the artificial tribological layer possessed not only the load-carrying capacity of Fe_2O_3,but also the lubricative capacity of MoS_2.These two simultaneous capacities could improve the friction and wear properties of H13 steel further. An artificial tribological layer was formed on the worn surface during sliding, through supplying MoS_2, Fe_2O_3 or their equiponderant mixtures onto the sliding interface of H13 / GCr15 steels. The effect of this tribological layer on the wear behavior of H13 steel was studied. Worn surfaces and subsurfaces of H13 steel were thoroughly characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS); the wear mechanisms were explored. the research results demonstrates that tribological layer did not exist during sliding of H13 steel with no additive, but it formed with the addition of MoS_2, Fe_2O_3 or their equiponderant mixtures. There was no tribological layer, the wear rate rapidly increased with an increase of the load. In this case, adhesive and abrasive wear prevailed.As the additives were supplied, the artificial tribological layer was observed to be immediately formed and stably existed on worn surfaces. this tribological layer p abrasion rate and friction coefficient were significantly decreased. MOS_2 as tribological layer seemed to present more obvious protective function than Fe_2O_3.By supplying their mixture, the artificial tribological layer possessed not only the load -carrying capacity of Fe_2O_3, but also the lubricative capacity of MoS_2. these two simultaneous capacities could improve the friction and wear properties of H13 steel further.