以铁 邻菲啉及铁 2 ,2′ 联吡啶配合物为催化剂 ,常压氧气为氧化剂 ,在 110℃对乙基苯、正丙苯、正丁苯及对二甲苯等烷基苯进行氧化 ,得到了相应的酮和醇 ;讨论了温度、底物与催化剂物质的量之比及烷基苯侧链对催化剂催化性能的影响 . Oxidation of alkyl benzenes, such as ethylbenzene, n-propylbenzene, n-butylbenzene and para-xylene, was carried out at 110 ℃ using iron-phenanthroline and iron2,2’bipyridine as catalyst and atmospheric oxygen as oxidant The corresponding ketones and alcohols were obtained. The effects of temperature, the ratio of the amount of substrate to the catalyst, and the side chain of alkylbenzene on the catalytic performance of the catalyst were discussed.