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研究了Ｚｒ部分替代稀土ＲＥ对ＲＥ（ＮｉＣｏＭｎＴｉ）。合金的相结构及电化学性能的影响．结果表明，在０＜ｘ≤０.３的组成范围内． ＲＥ１－ｘＺｒｘ（ＮｉＩＣｏＭｎＴｉ）５合金中均出现 ＺｒＮｉ。相，且其含量随 Ｚｒ替代量。的增加而增多； ＬａＮｉ。主相的晶胞体积随。的增加而增大，而ｚｒｍ。相的晶胞体积则逐渐减小因ＺｒＮｉ５第二相的形成，ＲＥ１－ｘＺｒｘ（ＮｉＣｏＭｎＴｉ）。合金的最大放电容量随 Ｚｒ替代量ｘ的增加而降低． ＺｒＮｉｓ相以连续网状沿 ＬａＮｉ５主相的晶界分布，对贮氢合金晶粒起了微包覆的保护作用，减轻了充放电循环过程中合金的粉化和氧化，从而显著提高了合金的循环稳定性．
The partial substitution of Zr for RE (NiCoMnTi) was studied. Phase Structure and Electrochemical Properties of Alloys. The result shows that it is within the composition range of 0
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