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Samarium substituted lithium manganese oxide powders were successfully prepared by molten-salt synthesis(MSS) using eutectic mixture of LiCl,SmCl3.6H2O and MnO2 salt at 700 °C.The synthesis was carried out in open atmosphere.The crystalline powders were characterized for their phase identification using X-ray diffraction(XRD) analysis.The physico-chemical properties of the samarium substituted lithium manganese oxide powders were investigated by thermal analysis(TGA/DTA),FT-IR spectroscopy,EDAX,electron paramagnetic resonance spectroscopy(EPR) and scanning electron microscopy(SEM).This investigation showed the possible methodology for obtaining pure LiSm0.01Mn1.99O4 at low temperature.
Samarium substituted lithium manganese oxide powders were successfully prepared by molten-salt synthesis (MSS) using eutectic mixture of LiCl, SmCl3.6H2O and MnO2 salt at 700 ° C. The synthesis was carried out in open atmosphere. The crystalline powders were characterized for their The physico-chemical properties of the samarium substituted lithium manganese oxide powders were investigated by thermal analysis (TGA / DTA), FT-IR spectroscopy, EDAX, electron paramagnetic resonance spectroscopy (EPR) and scanning electron microscopy (SEM). This investigation showed the possible methodology for obtaining pure LiSm0.01Mn1.99O4 at low temperature.