氟电极是除pH玻铂电极之外最成熟,应用最广泛、最普遍的一种选择电极。国外早在一九七三年就已推荐作为测定工业废水中氟的标准分析方法。氟电极的研制及其应用罗上庚和刘开祥都作过专门的介绍和评述。本文就近几年国内外氟电极的研制、应用及有关方面的研究工作作一简单介绍。早期用以制作氟电极的单晶为纯氟化铼单晶。在氟化铼单晶内进行“掺杂”,对电极 Fluoride electrode is the most mature, the most widely used and the most common type of selection electrode besides pH glassy platinum electrode. Abroad as early as 1973 has been recommended as a standard method for the determination of fluorine in industrial wastewater. Development of fluorine electrode and its application Luo Shanggeng and Liu Kaixiang made a special introduction and review. This article in recent years at home and abroad fluoride electrode research and application of related research work for a brief introduction. The early single crystal used to make the fluorine electrode was pure rhenium fluoride single crystal. In the rhenium fluoride single crystal “doping”, the counter electrode