Enhancement of Photocurrent Generation of a Novel Stilbazolium Dye Dimer in LB Monolayer Films

来源 :Chinese Chemical Letters | 被引量 : 0次 | 上传用户:Bryson
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A novel dye dimer, bis-{[1-(N-hexadecyl-4-pyridinium)-2-(4-N, N-dimethylamino- phenyl)] ethenyl}methane diiodide (C16BP) was synthesized, and the photoelectrochemistry of the dye Langmuir-Blodgett monolayer modified ITO electrode was investigated. For comparison, the photoelectrochemistry of the monomer (E)-N-hexadecyl-4-[2-(4-N, N-dimethylaminophenyl) ethenyl] pyridinium iodide (C16P) was also measured. The results show that the photocurrent generation property of the dimer is enhanced. The photocurrent generation quantum yield is 0.38% for C16BP, while that for C16P is 0.23%. A Novel dye dimer, bis - {[1- (N-hexadecyl-4-pyridinium) -2- (4-N, N- dimethylamino- phenyl)] ethenyl} methane diiodide (C16BP) was synthesized, and the photoelectrochemistry of the dye Langmuir-Blodgett monolayer modified ITO electrode was investigated. For comparison, the photoelectrochemistry of the monomer (E) -N-hexadecyl- 4- [2- (4-N, N-dimethylaminophenyl) ethenyl] pyridinium iodide (C16P) was also The results show that the photocurrent generation property of the dimer is enhanced. The photocurrent generation quantum yield is 0.38% for C16BP while while for C16P is 0.23%.
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