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以Cu(OAc)2.H2O和草酸、1,4-双(咪唑基-1-甲基)苯(bix)为原料,采用水热法合成了一维链状配位聚合物[CuI(bix)1.5(CH3COO)]n.(0.5nbix).(5nH2O),并对其进行了元素分析、红外光谱表征和X-射线单晶衍射测定.该配合物属于三斜晶系,P-1空间群,a=12.1092(19),b=12.5078(19),c=13.021(4),α=104.213(3),β=97.859(4),γ=117.917(2),V=1614.8(6)3,Z=2,Dc=1.397g/cm3,μ=0.734mm-1,F(000)=704,R1=0.0655,wR2=0.1859.
One-dimensional chain-like coordination polymers [CuI (bix)] were synthesized by hydrothermal method using Cu (OAc) 2.H2O and oxalic acid and 1,4-bis ) 1.5 (CH3COO)] n. (0.5nbix). (5nH2O) were synthesized and characterized by elemental analysis, IR and X-ray single crystal diffraction. The complex belongs to the triclinic system, A = 12.1092 (19), b = 12.5078 (19), c = 13.021 (4) , α = 104.213 (3), β = 97.859 (4), γ = 117.917 (2), V = 1614.8 ) 3, Z = 2, Dc = 1.397g / cm3, μ = 0.734mm-1, F (000) = 704, R1 = 0.0655, wR2 = 0.1859.