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5. Copper catalyzed borylative cyclization of 3-arylallyl carbamoyl chloride with B2pin2:stereoselectiv

Copper catalyzed borylative cyclization of 3-arylallyl carbamoyl chloride with B2pin2:stereoselectiv

来源 :中国化学快报（英文版） | 被引量 : 0次 | 上传用户：zhaodehu10000

【摘 要】

：

Borylative cyclization of E-3-arylallyl carbamoyl chlorides is achieved through copper catalyzed intramolecular carboboration with B2pin2. 2-Aryl-3-boryl-γ-lactams are formed with exclusive cis-diastereoselectivity. CuBr-Dppp combination gives the best ou

【作 者】

：

Mei-Hua Shen Ting-Biao Wan Xiu-Rong Huang Yan Li Dan-Hua Qian Hua-Dong Xu Defeng Xu 

【机 构】

：

Jiangsu Key Laboratory of Advanced Catalytic Materials&Technology,School of Pharmacy,Changzhou Unive

【出 处】

：

中国化学快报（英文版）

【发表日期】

：

2021年7期

【关键词】

：

Carboboration Borylative cyclization Copper catalysis Allyl carbamoyl chloride B 

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Borylative cyclization of E-3-arylallyl carbamoyl chlorides is achieved through copper catalyzed intramolecular carboboration with B2pin2. 2-Aryl-3-boryl-γ-lactams are formed with exclusive cis-diastereoselectivity. CuBr-Dppp combination gives the best outcomes. The substrate scope is profiled.

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