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Fe (Ⅲ)-2,9,16,23-tertracarboxy-phthalocyanine (Fe (Ⅲ)-taPc) was synthesized, and bonded to polystyrene (PS) with covalence by Friedel-Crafts reaction to form a new polymer (Fe (Ⅲ)-taPc-PS) (polymer (Ⅱ)). UV-VIS and Infrared spectra indicated that Fe (Ⅲ)-t