论文部分内容阅读
含有各种类型配体的过渡金属配合物化学是一个非常活跃的领域。当代化学的一个热点就是有机金属配合物和键。其中由于大多数含磷配体的配合物可作为各种重要反应的催化剂或催化剂前体已经引起了人们的浓厚兴趣［1-2］。在研究过渡金属原子簇电子结构和成键规律时，由于过渡金属
Transition metal complex chemistry with various types of ligands is a very active area. One of the hot spots in contemporary chemistry is organometallic complexes and bonds. Among them, most of phosphorus-containing ligand complexes can serve as catalysts for various important reactions or catalyst precursors have attracted great interest [1-2]. In studying the transition metal cluster electronic structure and bonding rules, due to the transition metal