由于液/液界面可以看作是模拟生物膜或人造膜的简单模型,研究在此其上的电子转移过程对理解生物体复杂的生理变化过程具有重要意义。薄层伏安法因其简单、易操作等优点成为研究液/液界面电子转移过程的有力手段,因此对该方法的定量分析理论研究显得尤为重要。本文综述了薄层伏安法液/液界面电子转移速率理论近年来的研究进展,并对其可能的影响因素进行了分析。 Since the liquid / liquid interface can be regarded as a simple model for simulating biomembrane or artificial membrane, the study of the electron transfer process here is very important for understanding the complicated physiological changes of organisms. Thin-layer voltammetry is a powerful method to study the electron transfer process at the liquid / liquid interface because of its simplicity and easy operation. Therefore, the quantitative analysis of this method is particularly important. This review summarizes recent advances in the theory of liquid / liquid interface electron transfer rate of thin-film voltammetry, and analyzes its possible influencing factors.