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有关铂族的阴离子交换行为的工作是很多的等进行过阳离子交换柱层析的研究,据报导,只有Stevenson的工作解决了非挥发性铂族的多元混合物的分离问题。本文利用国产新华牌(1号,快速)经磷酸化滤纸(铵型),以希矿酸和盐类作展开剂,试液为0.5N矿酸,采用上行法研究了铂族的交换行为。结果证明,很容易分离三元以上混合物,而且斑点集中,展开迅速。实验结果:展开剂酸度、氯离子浓度以及盐类
Work on anion exchange behavior of the platinum group is much more studied by cation exchange column chromatography and it is reported that only Stevenson’s work has solved the problem of separation of non-volatile platinum group multi-component mixtures. In this paper, the domestic Xinhua brand (No. 1, fast) through the phosphorylation of filter paper (ammonium type), with the Greek acid and salt as a developing agent, test solution 0.5N mineral acid, the upside method to study the platinum group exchange behavior. The results show that it is easy to separate ternary mixture, and the spot focus, expand rapidly. Experimental Results: Developing Agent Acidity, Chloride Ion Concentration and Salts