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用AM1方法研究了碳酸和碳酸酯的热消除反应．发现迁移基团R和基团R’共同制约这类吸热反应的活化能。
AM1 method was used to study the thermal elimination of carbonic acid and carbonate. It is found that the migration group R and the group R ’jointly constrain the activation energy of such endothermic reactions.