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(Et4N)[Ni2(SC6H5)2(S2CS)2],Mr= 844. 68; monoclinic P21/c, a = 16. 951(3), b = 11. 151(3), c=20. 428(2)(?) ,β=99. 03(2)°, V = 3813(3)(?)3, Z = 4, Dm = l. 48, Dx = 1. 471 gem-3, graphite-monochromated MoKa=0. 71073 (?), μ=14. 4cm-1, F(000) = 1776; T’ = 295K, R = 0.061, Rw =0.072 for 5586 unique observed reflections, and 211 parameters. The structure of the complex consist of discrete [Ni2(μ-SC6H5)2(S2CS)2]2- complex anions and tetraethylammonium cations. In each anion nickel (Ⅱ) is distorted square planar coordinated with four atoms, two bridging atoms from the benzene-thiolato and two from the trithio-car-bonate, SCS22- ligand. The structure has the synendo conformation[1].
(Et4N) [Ni2 (SC6H5) 2 (S2CS) 2], Mr = 844. 68; monoclinic P21 / c, a = 16. 951 (3), b = 11. 151 (3), c = 2) (?), Β = 99.03 (2) °, V = 3813 (3) (?) 3, Z = 4, Dm = 1.48, Dx = 1.471 gem-3, graphite-monochromated MoKa = 0. 71073 (?), Μ = 14.4 cm -1, F (000) = 1776; T ’= 295K, R = 0.061, Rw = 0.072 for 5586 unique observed reflections, and 211 parameters. The structure of the complex consists of discrete [Ni2 (μ-SC6H5) 2 (S2CS) 2] 2- complex anions and tetraethylammonium cations. In each anion nickel (Ⅱ) is distorted square planar coordinated with four atoms, two bridging atoms from the benzene-thiolato and two from the trithio-car-bonate, SCS22-ligand. The structure has the synendo conformation [1].