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By reacting(NH_4)_2 MoS_4,FeCl_2 and Me_2dtc Na at room temperature,we have synthesizedin one pot two single cubane-like cluster compounds,MoFe_3S_4(Me_2dtc)_5·CH_2Cl_2(1)and MoFe_3S_4-(Me_2dtc)_6·2CH_3CN(3),which were separated by stepwise crystallization.The structure of 3 wassolved and refined for 5183 reflections to final R value of 0.069.Compound 3 is a novel cluster posses-sing the highest core oxidation state[MoFe_3S_4]~(?) and contains two Me_2dtc bridges.The structuralfeature of 3 is reported and the observation that several single cubane-like clusters containing variousoxidation states can coexist in an assembly system is discussed.
By reacting (NH_4) _2 MoS_4, FeCl_2 and Me_2dtc Na at room temperature, we have synthesizedin one pot two single cubane-like cluster compounds, MoFe_3S_4 (Me_2dtc) _5 · CH_2Cl_2 (1) and MoFe_3S_4- (Me_2dtc) _6 · 2CH_3CN ), which were separated by stepwise crystallization. The structure of 3 wassolved and refined for 5183 reflections to final R value of 0.069. Compound 3 is a novel cluster posses-sing the highest core oxidation state [MoFe_3S_4] ~ (?) and contains two Me_2dtc bridges. The structural feature of 3 is reported and the observation that several single cubane-like clusters containing variousoxidation states can coexist in an assembly system is discussed.