,Microstructure and Corrosion Performance of Oxide Coatings on Aluminium by Plasma Electrolytic Oxid

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Ceramic coatings are fabricated on pure aluminium by plasma electrolytic oxidation (PBO) in three kinds of electrolyte systems [E1: 0.05M NaOH+0.033M Na2SiO3, E2: 0.025M NaOH+0.008M (NaPO3)6 and E3: 0.025MNaOH+0. 066M Na2 SiO3+0. 008M (NaPO3)6]. The voltage-time responses show that the PEO process of E2 has the highest discharging voltage, which results in the biggest pores and heaviest cracks on the smfaces. X-ray diffraction results show that coatings produced in E1 and E3 are mainly composed of γ-Al2 O3 and mullite, while coatings produced in E2 are mainly composed of α-Al2O3. After PEO treatment the corrosion resistance of aluminium is improved significantly and the coatings produced in E3 perform the best corrosion resistance.
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