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A palladium(Ⅱ) complex, PdLCl2·PdCl4, L=4-bromo-2,6-bis(N,N-diethylaminomethylene)pyridine, was synthesized and its crystal structure was determined by X-ray analysis. The complex crystallizes in monoclinic system with space group Cc, a=0.845 1(17) nm, b=1.836 5(4) nm, c=2.715 8(5) nm, β=93.99(3)°, V=4.204 8(15) nm3, Z=4, R1=0.037 7 and wR2=0.076 9. The coordination geometry of the Pd atom in the cation is a slightly distorted square planar, with one pyridyl N and two N atoms of the diethylamine ligand, together with one Cl atom. The dihedral angle between the square planar (N3PdCl) and the pyridyl ring is 10.3(4)°. CCDC: 623421.
A complex of palladium (II) complex, PdCl 2 · PdCl 4, L = 4-bromo-2,6-bis (N, N-diethylaminomethylene) pyridine was synthesized and its crystal structure was determined by X-ray analysis. a = 0.845 1 (17) nm, b = 1.836 5 (4) nm, c = 2.715 8 (5) nm, β = 93.99 (3) °, V = 4.204 8 Z = 4, R1 = 0.0377 and wR2 = 0.076 9. The coordination geometry of the Pd atom in the cation is a slightly distorted square planar, with one pyridyl N and two N atoms of the diethylamine ligand, together with one Cl atom. The dihedral angle between the square planar (N3PdCl) and the pyridyl ring is 10.3 (4) °. CCDC: 623421.