Silicon isotope analysis traditionally uses a standard-sample bracketing(SSB) method that relies upon greater instrument stability than can be consistently expected. The following proposed method reduces the level of instrumental stability required for the analysis process and provides a valid solution for high-precision and accurate studies of Si isotopic compositions. Rock samples were dissolved by using alkali fusion and acidification.Silicon isotopes were purified with an ion exchange resin.Interfering peaks for isotopes were separated by using a Nu Plasma 1700 multi-collector inductively coupled plasma mass spectrometry(MS) system in high-resolution mode(M/DM [ 8000 RP). Two magnesium isotopes(~(25)Mg and~(26)Mg) and three silicon isotopes(~(28)Si,~(29) Si, and~(30)Si) were analyzed in the same data collection cycle. Mg isotopes were used as an internal standard to calibrate the mass discrimination effects in MS analysis of Si isotopes in combination with the SSB method in order to reduce the effects of MS interference and instrumental mass discrimination on the accuracy of measurements. The conventional SSB method without the Mg internal standard and the proposed SSB method with Mg calibration delivered consistent results within two standard deviations.When Mg was used as an internal standard for calibration,the analysis precision was better than 0.05 % amu. Silicon isotope analysis traditionally uses a standard-sample bracketing (SSB) method that relies upon greater instrument stability than can be consistently expected. The following proposed method reduces the level of instrumental stability required for the analysis process and provides a valid solution for high-precision and accurate studies of Si isotopic compositions. Rock samples were dissolved by using alkali fusion and acidification. Silicon isotopes were purified with an ion exchange resin. Interfering peaks for isotopes were separated by using a Nu Plasma 1700 multi-collector inductively coupled plasma mass spectrometry MS) system in high-resolution mode (M / DM [8000 RP). Two magnesium isotopes (25 Mg and 26 Mg) and three silicon isotopes and ~ (30) Si) were analyzed in the same data collection cycle. Mg isotopes were used as an internal standard to calibrate the mass discrimination effects in MS analysis of Si isotopes in combination with the SSB method in order t o reduce the effects of MS interference and instrumental mass discrimination on the accuracy of measurements. The conventional SSB method without the Mg internal standard and the proposed SSB method with Mg calibration delivered the results within two standard deviations. for calibration, the analysis precision was better than 0.05% amu.