论文部分内容阅读
对由非光学活性底物不对称构建磷手性中心的方法进行综述,根据底物的结构以及机理的不同分为两类介绍,分别是前对映异构体的去对称化以及不同取代底物的化学拆分.
The methods for asymmetric formation of phosphorus chiral centers from non-optically active substrates are reviewed. According to the structure and mechanism of the substrates, two types of introduction are introduced: desymmetrization of the enantiomers and substitution of different substrates Chemical splitting.